Triimidazolium Salts Left H3·(PF6)3 and its NHC (no-Heterocyclic carbene) Ag(I) complexes 1 were prepared and characterized. Left H3·(PF6)3 and 1 This was verified by X-ray diffraction analysis. Left H3·(PF6)3Two imidazoles were located on the same side of the triazinetrione face, and the third imidazole was located on the other side of the triazinetrione face. 1 It had a scorpion-like structure with a 12-membered macrometallocycle. 1 In the case of H2PO4– It was studied based on the fluorescence spectrum. 1H NMR, MS, IR. 1H2PO4– (hair= 3.3 × 104 Ma-1)teeth, 1 Had a strong association ability with H2PO4–Detection limit (2.54 × 10-10 mol/L) is detected by 1 To H2PO4– It was sensitive.
Zhao, Z., Yang, Y., Han, X., Liu, R., & Liu, Q. (2024). Triazinetrione-based scorpion-shaped NHC Ag(I) complexes: Preparation, structure and recognition towards dihydrogen phosphate. Journal of Organometallic Chemistry123328. https://doi.org/10.1016/j.jorganchem.2024.123328
